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5. 6. 7. 8. Cookson, R. ; Costa, S. M. ; Hudec, J. Chem. Commun. 1969, 753. ; Sakurai, H. Nippon Kagaku Kaishi 1984, 152. Lewis, F. ; Bassani, D. ,I. Photochem. Photobiol. A. 1994, 81, 13. ; Matsunaga, K. J. Chem. , Chem. Commun. 1972, 313. Lewis, F. -I. J. Am. Chem. Soc. 1977, 99, 7991. Yang, N. ; Libman, J. 3'. Am. Chem. Soc. 1973, 95, 5783. Barltrop, J. A. Pure Appl. Chem. 1973, 33, 179. (a) Lewis, F. D. Adv. Photochem. 1986, 13, 165. (b) Lewis, E D. Acc. Chem. Res. 1986, 19, 401. 9. Lewis, F.
The formation of 62 from the intramolecular reaction of 58 and of 5 from the intermolecular reaction of anthracene and dimethylaniline 29 may also occur via C-C bond formation in the biradical or radical pair intermediates. The photochemical behavior of several families of (N-methylaminoalkyl)arenes and arylolefins have been investigated in the author's laboratory. No quenching of locally excited phenanthrene fluorescence is observed for the 1-(N-methylaminoalkyl)phenanthrenes 71 and 72 and no intramolecular adducts are formed.
Am. Chem. Soc. 1984, 106, 708. 26. Lewis, F. ; Simpson, J. T. ,/. Phys. Chem. 1979, 83, 2015. 27. ; Lehnig, M. J. Photochem. , A 1994, 84, 221. 28. Lewis, F. ; Simpson, J. T. J. A~n. Chem. Soc. 1982, 104, 1924. 29. ; Sakurai, H. Bull. Chem. Soc. Jpn. 1981, 54, 2352. 30. ; Gilbert, A. Tetrahedron 1977, 33, 2459. 38 FREDERICK D. LEWIS 31. ; Hatano, H. J. Chem. , Chem. Commun. 1989, 206. ; Miyagawa, H. J. Chem. , Chem. Commun. 1988, 1183. ; Simpson, J. T. J. Org. Chem. 1981, 46, 1077. ; Frisch, I.