By Gribble Gordon W. and Joule John A. (Eds.)

This can be the 16th annual quantity of growth in Heterocyclic Chemistry, and covers the literature released in the course of 2003 on lots of the very important heterocyclic ring systems.This quantity opens with really expert reports. the 1st covers 'Lamellarins: Isolation, job and synthesis' an important crew of biologically lively marine alkaloids and the second one discusses 'Radical Additions to Pyridines, Quinolines and Isoquinolines'. the rest chapters learn the hot literature at the universal heterocycles so as of accelerating ring dimension and the heteroatoms current.

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Org. Chem. 1985, 50, 3423. A. Citterio, A. Gentile, F. Minisci, M. Serravalle, S. Ventura, Tetrahedron 1985, 41,617. K. P. Sloan, V. Snieckus, Tetrahedron Lett. 1985, 26, 6001. C. Giordano, F. Minisci, E. Vismara, S. Levi, J. Org. Chem. 1986, 51,536. F. Minisci, E. Vismara, F. Fontana, G. Morini, M. Serravalle, C. Giordano, J. Org. Chem. 86T5973 86TL3187 86TL3239 87JOC730 88BSF67 89CC757 90CC 1069 G. Heinisch, G. LOtsch, Tetrahedron 1986, 42, 5973. E. Vismara, M. Serravalle, F. Minisci, Tetrahedron Lett.

T pyridine: below 5%. Scheme 1 Various substituted pyridines have been examined in the reaction, as indeed have various radical intermediates. These results have been collated in earlier reviews <63AHC131, 74AHC123, 84CHEC-I293> and there seems little merit in repeating them in full here. In almost every case, product yields were low and selectivity poor, making them redundant for synthetic purposes. Some illustrative examples are highlighted in Schemes 2 to 7, together with an indication of the regioisomeric ratios reported.

Chem. 1990, 55, 6317. V. Farinas, B. Krishnan, J. Am. Chem. Soc. 1991, 113, 9585. Y. K. R. J. Schemer, Helv. Chim. Acta 1992, 75, 1721. N. Mitchell, Synthesis 1992, 803. A. Fttrstner, Angew. Chem. Int. Ed. Engl. 1993, 32, 164. R. F. C. Coll, Aust. J. Chem. 1993, 46, 489. P. D. Singer, Chem. Rev. 1993, 93, 2117. S. S. J. Capon, Aust. J. Chem. 1994, 47, 1919. A. Ftirstner, A. Hupperts, A. Ptock, E. Janssen, J. Org. Chem. 1994, 59, 5215. A. Rudi, I. Golberg, Z. Stein, F. Frolow, Y. Benayahu, M. Schleyer, Y.

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